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You can start using Chatous right away under a random username, but if you make your own account you'll be able customize the name people see, save your friends list, and login to your account from the mobile app.
Or, if you're looking for more of a one-on-one messaging service, see this Apps for Free Video Chat on Your Computer list.
You can text or broadcast your video with everyone, as well as see anyone else who is publicly broadcasting.
However, you can also privately message and video chat with any other online user. More » 321 Chat is a video and text chatting website that lets you join rooms of different topics, like one for teens, seniors, singles, Asians, people in their 20s, religion, kids, etc.
You can add a description about yourself and even include links to your favorite You Tube videos so that other Face Flow users can get a feel of the music or videos you're into.
You have to make a free user account at Face Flow before you can have face-to-face chats or text conversations with other users.